| Автор | Reddy, Venkata S. |
| Автор | Krishnamurthy, Setharampattu S. |
| Автор | Nethaji, Munirathinam |
| Дата выпуска | 1995 |
| dc.description | The reactions of the mononuclear cyclodiphosphazane complexes, cis-[Mo(CO)4{cis-[PhNP(OR)]2}2] with [Mo(CO)4(nbd)](nbd = norbornadiene), [Mo(CO)4(NHC5H10)2] or [MCl2(cod)](cod = cycloocta-1,5-diene) afforded the homobimetallic complexes, [Mo2(CO)8{µ-cis-[PhNP(OR)]2}2](R = C6H4Me-p 5 or CH2CF3 6) or the heterobimetallic complexes, [Mo(CO)4{µ-cis-[PhNP(OR)]2}2MCl2](R = C6H4Me-p; M = Pd 7 or Pt 8). In all the above complexes, the two metal moieties are bridged by two cyclodiphosphazane ligands. The reactions of the mononuclear complexes, cis-[M(CO)4(A){cis-[PhNP(OC6H4Me-p)]2}] with [M⠲Cl2(cod)] afforded the trinuclear complexes, cis-[M⠲Cl2[M(CO)4(A){cis-[PhNP(OC6H4Me-p)]2}]2](M⠲= Pd, M = Mo, A = P(OMe)3 10; M⠲= Pt, M = Mo, A = P(OMe)3 11; M⠲= Pd, M = W, A = NHC5H10 12; M⠲= Pt, M = W, A = NHC5H10 13). The structure of the complex 5 has been determined by single-crystal X-ray crystallography. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Di- and tri-metallic complexes containing two bridging cyclodiphosphazane ligands: the crystal structure of [MO2(CO)8{µ-cis-[PhNP(OC6H4Me-p)]2}2] |
| Тип | research-article |
| DOI | 10.1039/DT9950001933 |
| Electronic ISSN | 1364-5447 |
| Print ISSN | 1472-7773 |
| Журнал | Journal of the Chemical Society, Dalton Transactions |
| Первая страница | 1933 |
| Последняя страница | 1938 |
| Выпуск | 12 |
| Библиографическая ссылка | Kamalesh Babu, Organometallics, in the press |
| Библиографическая ссылка | Balakrishna, Coord. Chem. Rev., 1994, 129, 1 |
| Библиографическая ссылка | Reddy, J. Organomet. Chem., 1992, 438, 99 |
| Библиографическая ссылка | Reddy, J. Chem. Soc., Dalton Trans., 1994, 2661 |
| Библиографическая ссылка | D. F. Shriver and M. A.Drezdzon, The Manipulation of Air-sensitive Compounds, 2nd edn., Wiley, New York, 1986. |
| Библиографическая ссылка | D. D. Perrin and W. L. F.Armarego, Purification of Laboratory Chemicals, 3rd edn., Pergamon, Oxford, 1988. |
| Библиографическая ссылка | Eisch, Organomet. Synth., 1965, 1, 122 |
| Библиографическая ссылка | Eisch, Organomet. Synth., 1965, 1, 124 |
| Библиографическая ссылка | Darensbourg, Inorg. Chem., 1978, 17, 2680 |
| Библиографическая ссылка | Drew, Inorg. Synth., 1972, 13, 52 |
| Библиографическая ссылка | Drew, Inorg. Synth., 1972, 13, 48 |
| Библиографическая ссылка | G. M. Sheldrick , SHELXS 86, A program for crystal structure solution, University of Göttingen, Göttingen, 1986. |
| Библиографическая ссылка | G. M. Sheldrick , SHELX 76, A program for crystal structure determination, University of Cambridge, 1976. |
