Автор |
Djordjevi?, C. |
Автор |
Nyholm, R. S. |
Автор |
Pande, C. S. |
Автор |
Stiddard, M. H. B. |
Дата выпуска |
1966 |
dc.description |
The action of iodine on the hexacarbonyls of chromium molybdenum, and tungsten has been studied. When heated in a sealed tube with iodine at 150°, hexacarbonylchromium yields a product of indefinite composition, whilst the carbonyls of molybdenum and tungsten both produce the tri-iodide of the metal. Tungsten tri-iodide has not been reported previously. These tri-iodides are reactive and form the complexes M(Diars)2I2(Diars =o-phenylenebisdimethylarsine) and Mopy3I3. |
Формат |
application.pdf |
Издатель |
Royal Society of Chemistry |
Название |
Reaction of iodine with Group VI hexacarbonyls: tri-iodides of molybdenum and tungsten and their derivatives |
Тип |
research-article |
DOI |
10.1039/J19660000016 |
Print ISSN |
0022-4944 |
Журнал |
Journal of the Chemical Society A: Inorganic, Physical, Theoretical |
Первая страница |
16 |
Последняя страница |
17 |