Behaviour of carbon dioxide and nitrous oxide in active nitrogen
Campbell, I. M.; Thrush, B. A.
Журнал:
Transactions of the Faraday Society
Дата:
1966
Аннотация:
Carbon dioxide and nitrous oxide are decomposed by active nitrogen to yield oxygen atoms. These molecules are dissociated by collision with excited N2 molecules in the B <sup>3</sup>Î g state which emits the nitrogen afterglow. The rate constants for this process are (5.1±0.8)à 10<sup>13</sup> and (3.5±0.4)à 10<sup>13</sup> cm<sup>3</sup> mole sec<sup>â 1</sup> at 196°K for CO2 and N2O respectively. Reactions (2) and (3) N+O+M = NO+M (2) N+N+M = N2+M (3) have the following rate constants in cm<sup>6</sup> mole<sup>â 2</sup> sec<sup>â 1</sup>: [graphic omitted]
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