| Автор | Li, Bo-Yan |
| Автор | Hu, Yun |
| Автор | Liang, Yi-Zeng |
| Автор | Xie, Pei-Shan |
| Автор | Ozaki, Yukihiro |
| Дата выпуска | 2006 |
| dc.description | Secured principal component regression is modified for the qualitative analysis of chromatographic fingerprint data sets of herbal samples with residual concentrations. After chromatographic shift-correction and autoscaling are performed on the data, this modified secured principal component regression (msPCR) can detect unexpected chromatographic features in various herbal fingerprints. The successful application of msPCR to two real herbal medicines of Erigeron breviscapus from different geographical origins and Ginkgo biloba from various sources or vendors demonstrates that the proposed method can detect reasonably unexpected features differing from the regulars or not being modeled. From a chemical point of view, the causes have also been explained to corroborate the results. Moreover, it presents a viable approach for the qualitative evaluation of diverse herbal objects with a regular class of chromatographic fingerprints. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Modified secured principal component regression for detection of unexpected chromatographic features in herbal fingerprints |
| Тип | research-article |
| DOI | 10.1039/b513365c |
| Electronic ISSN | 1364-5528 |
| Print ISSN | 0003-2654 |
| Журнал | Analyst |
| Том | 131 |
| Первая страница | 538 |
| Последняя страница | 546 |
| Аффилиация | Li Bo-Yan; College of Chemistry and Chemical Engineering, Research Center of Modernization of Chinese Herbal Medicines, Central South University; Department of Chemistry and Research Center for Near-Infrared Spectroscopy, School of Science and Technology, Kwansei-Gakuin University |
| Аффилиация | Hu Yun; Department of Chemistry and Research Center for Near-Infrared Spectroscopy, School of Science and Technology, Kwansei-Gakuin University |
| Аффилиация | Liang Yi-Zeng; College of Chemistry and Chemical Engineering, Research Center of Modernization of Chinese Herbal Medicines, Central South University |
| Аффилиация | Xie Pei-Shan; College of Chemistry and Chemical Engineering, Research Center of Modernization of Chinese Herbal Medicines, Central South University |
| Аффилиация | Ozaki Yukihiro; Department of Chemistry and Research Center for Near-Infrared Spectroscopy, School of Science and Technology, Kwansei-Gakuin University |
| Выпуск | 4 |
| Библиографическая ссылка | Bauer, Drug Inf. J., 1998, 32, 101 |
| Библиографическая ссылка | Gong, J. Chromatogr., A, 2003, 1002, 25 |
| Библиографическая ссылка | Li, J. Sep. Sci., 2004, 27, 581 |
| Библиографическая ссылка | Hasler, J. Chromatogr., 1992, 605, 41 |
| Библиографическая ссылка | Layloff, Pharm. Technol., 1991, 15, 146 |
| Библиографическая ссылка | Kirchhoefer, J. AOAC Int., 1992, 75, 577 |
| Библиографическая ссылка | Anon, Gold Sheet, 1994, 28, 1 |
| Библиографическая ссылка | Welsh, Anal. Chem., 1996, 68, 3473 |
| Библиографическая ссылка | Valentão, J. Agric. Food Chem., 1999, 47, 4579 |
| Библиографическая ссылка | Xie, Trad. Chin. Drug Res. Clin. Pharmacol., 2001, 12, 141 |
| Библиографическая ссылка | Lin, J. Chromatogr., A, 2000, 876, 87 |
| Библиографическая ссылка | Gong, J. Chromatogr., A, 2001, 909, 237 |
| Библиографическая ссылка | Hu, Acta Chim. Sin., 2003, 61, 1466 |
| Библиографическая ссылка | Cheng, J. Chem. Inf. Comput. Sci., 2003, 43, 1068 |
| Библиографическая ссылка | Collantes, Anal. Chem., 1997, 69, 1392 |
| Библиографическая ссылка | Cheng, J. Chem. Inf. Comput. Sci., 2003, 43, 1959 |
| Библиографическая ссылка | Vogt, J. Chemom., 2003, 17, 225 |
| Библиографическая ссылка | Vogt, Anal. Chem., 2003, 75, 3050 |
| Библиографическая ссылка | Wold, Chemom. Intell. Lab. Syst., 1987, 2, 37 |
| Библиографическая ссылка | Zhang, Chemom. Intell. Lab. Syst., 2003, 67, 175 |
| Библиографическая ссылка | Vogt, Appl. Spectrosc., 1999, 53, 1352 |
| Библиографическая ссылка | Li, Anal. Chim. Acta, 2004, 514, 69 |
| Библиографическая ссылка | Barnes, Appl. Spectrosc., 1989, 43, 772 |
| Библиографическая ссылка | Barnes, J. Near Infrared Spectrosc., 1993, 1, 185 |
| Библиографическая ссылка | Dhanoa, J. Near Infrared Spectrosc., 1994, 2, 43 |
| Библиографическая ссылка | Guo, Anal. Chim. Acta, 1999, 382, 87 |
| Библиографическая ссылка | Bro, J. Chemom., 2003, 17, 16 |
| Библиографическая ссылка | Meloun, Talanta, 2002, 57, 721 |
| Библиографическая ссылка | Sticher, Planta Med., 1993, 59, 2 |
