Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase
Stenson, Philip A.; Marin-Becerra, Armando; Wilson, Claire; Blake, Alexander J.; McMaster, Jonathan; Schröder, Martin; Stenson Philip A.; School of Chemistry, The University of Nottingham; Marin-Becerra Armando; School of Chemistry, The University of Nottingham; Wilson Claire; School of Chemistry, The University of Nottingham; Blake Alexander J.; School of Chemistry, The University of Nottingham; McMaster Jonathan; School of Chemistry, The University of Nottingham; Schröder Martin; School of Chemistry, The University of Nottingham
Журнал:
Chemical Communications
Дата:
2006
Аннотация:
The binuclear [Ni(L)Fe(CO)3], 1, and trinuclear [Ni(L){Fe(CO)3}2], 2, complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via μ2-S bridging modes, C.dbd;N imine Ï -bonds and potential Niâ Fe bonding interactions.
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