High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons
Allan, David R.; Blake, Alexander J.; Huang, Deguang; Prior, Timothy J.; Schröder, Martin; Allan David R.; School of Chemistry, The University of Edinburgh; Blake Alexander J.; School of Chemistry, The University of Nottingham; Huang Deguang; School of Chemistry, The University of Nottingham; Prior Timothy J.; CCLRC Daresbury Laboratory; Schröder Martin; School of Chemistry, The University of Nottingham
Журнал:
Chemical Communications
Дата:
2006
Аннотация:
The mononuclear Pd(ii) complex cis-[PdCl2([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.
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