[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2? and pyrazine ligands
Manson, Jamie L.; Conner, Marianne M.; Schlueter, John A.; Lancaster, Tom; Blundell, Stephen J.; Brooks, Michael L.; Pratt, Francis L.; Papageorgiou, Thomas; Bianchi, Andreas D.; Wosnitza, Jochen; Whangbo, Myung-Hwan; Manson Jamie L.; Department of Chemistry and Biochemistry, Eastern Washington University; Conner Marianne M.; Department of Chemistry and Biochemistry, Eastern Washington University; Schlueter John A.; Materials Science Division, Argonne National Laboratory; Lancaster Tom; Clarendon Laboratory, Physics Department, Oxford University; Blundell Stephen J.; Clarendon Laboratory, Physics Department, Oxford University; Brooks Michael L.; Clarendon Laboratory, Physics Department, Oxford University; Pratt Francis L.; ISIS Facility, Rutherford-Appleton Laboratory; Papageorgiou Thomas; Hochfeld-Magnetlabor Dresden (HLD), Forschungszentrum Rossendorf; Bianchi Andreas D.; Hochfeld-Magnetlabor Dresden (HLD), Forschungszentrum Rossendorf; Wosnitza Jochen; Hochfeld-Magnetlabor Dresden (HLD), Forschungszentrum Rossendorf; Whangbo Myung-Hwan; Department of Chemistry, North Carolina State University
Журнал:
Chemical Communications
Дата:
2006
Аннотация:
[Cu(HF2)(pyz)2]BF4 consists of rare μ1,3 bridging HF2<sup>â </sup> anions and μ-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.
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