Model systems for flavoenzyme activity: Recognition and redox modulation of flavin mononucleotide in water using nanoparticles
Bayir, Ali; Jordan, Brian J.; Verma, Ayush; Pollier, Michael A.; Cooke, Graeme; Rotello, Vincent M.; Bayir Ali; Department of Chemistry, LGRT 701, 710 N. Pleasant St., University of Massachusetts; Jordan Brian J.; Department of Chemistry, LGRT 701, 710 N. Pleasant St., University of Massachusetts; Verma Ayush; Department of Chemistry, LGRT 701, 710 N. Pleasant St., University of Massachusetts; Pollier Michael A.; Department of Chemistry, LGRT 701, 710 N. Pleasant St., University of Massachusetts; Cooke Graeme; WestCHEM Centre for Supramolecular Electrochemistry, Department of Chemistry, Joseph Black Building, University of Glasgow; Rotello Vincent M.; Department of Chemistry, LGRT 701, 710 N. Pleasant St., University of Massachusetts
Журнал:
Chemical Communications
Дата:
2006
Аннотация:
We have used mixed monolayer protected gold clusters (MMPCs) to provide flavoenzyme model systems with a high affinity and ability to modulate cofactor reduction potential.
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