Isotope effect on the coupling constant1J(13C–H)
Sergeyev, Nickolay M.; Solkan, Vitalii N.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1975
Аннотация:
The negative isotope effect on the coupling constant <sup>1</sup> J(<sup>13</sup>Câ H){Î J=(γ H/γ D)[<sup>1</sup> J(<sup>13</sup>Câ D)]â <sup>1</sup> J(<sup>13</sup>Câ H)} has been confirmed by INDO FP calculations of the <sup>1</sup> J(<sup>13</sup>Câ H) coupling constant in methane by varying one of the Câ H distances.
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