Автор |
Barker, Geoffrey K. |
Автор |
Green, Michael |
Автор |
Spencer, John L. |
Автор |
Stone, F. Gordon A. |
Автор |
Taylor, Brian F. |
Автор |
Welch, Alan J. |
Дата выпуска |
1975 |
dc.description |
Reaction of closo-2,4-C2B5H7 with [Pt(styrene)-(PEt3)2] affords closo-2,3-[(Et3P)2]2-1,2,3,6 -CPt2CB5H7, whereas [Pt(1,5-C8H12)(PMe3)2] and 1,6-C2B8H10 gives nido-µ(4,8)-[(Me3P)2]- 7,8,10-CPtCB8H10 which on treatment with activated charcoal affords, nido-8,8-[(Me3P)2]-7,8,10-CPtCB8H10; the structural identity of the complexes was established by X-ray crystallography. |
Формат |
application.pdf |
Издатель |
Royal Society of Chemistry |
Название |
Synthesis of nido- and closo-diplatinacarborane complexes by direct insertion; crystal and molecular structures of closo-2,3-[(Et3P)2]2-1,2,3,6-CPt2CB5H7, nido-µ(4,8)-[(Me3P)2Pt]-8,8-[(Me3P)2]-7,8,10-CPtCB8H10and nido-8,8-[(Me3)2]-7,8,10-CPtCB8H10. |
Тип |
research-article |
DOI |
10.1039/C39750000804 |
Print ISSN |
0022-4936 |
Журнал |
Journal of the Chemical Society, Chemical Communications |
Первая страница |
804 |
Последняя страница |
805 |
Выпуск |
19 |