The tetracarbonyl trianions of manganese and rhenium, M(CO)4 3?
Ellis, John E.; Faltynek, Robert A.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1975
Аннотация:
Alkali metal reduction of M2(CO)10 or M(CO)5 <sup>â </sup>(M .dbd; Mn and Re) in hexamethylphosphoramide provides the first non-cluster binary metal carbonyl trianions, M(CO)4 <sup>3â </sup>, which are characterized by their spectral and chemical properties.
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