Автор | Emsley, James W. |
Автор | Lindon, John C. |
Автор | Tabony, James |
Дата выпуска | 1975 |
dc.description | Simultaneous measurement of proton and deuterium spectra of partially oriented 4-[<sup>2</sup>H1]pyridine by an INDOR experiment is shown to give an accurate measurement of the quadrupole coupling constant provided that vibrational averaging is used in the determination of orientation parameters. The effect of vibrational averaging on the structure of pyridine and [<sup>15</sup>N]-pyridine derived from N.M.R. data is found to be small. |
Формат | application.pdf |
Издатель | Royal Society of Chemistry |
Название | Effect of vibrational averaging on the quadrupole coupling constant of deuterium in 4-[2H1] pyridine determined from1H–{2H} INDOR n.m.r. of a partially oriented sample |
Тип | research-article |
DOI | 10.1039/F29757100579 |
Print ISSN | 0300-9238 |
Журнал | Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics |
Том | 71 |
Первая страница | 579 |
Последняя страница | 585 |