Supersilyl radicals from the dissociation of superdisilane observed by gas electron diffraction
Masters (née Hinchley), Sarah L.; Grassie, Duncan A.; Robertson, Heather E.; Hölbling, Margit; Hassler, Karl; Masters (née Hinchley) Sarah L.; School of Chemistry, University of Edinburgh; Grassie Duncan A.; School of Chemistry, University of Edinburgh; Robertson Heather E.; School of Chemistry, University of Edinburgh; Hölbling Margit; Institut für Anorganische Chemie, Technische Universität Graz; Hassler Karl; Institut für Anorganische Chemie, Technische Universität Graz
Журнал:
Chemical Communications
Дата:
2007
Аннотация:
The vapour produced upon mild heating of hexa-tert-butyldisilane (superdisilane) has been studied by gas electron diffraction and ab initio molecular orbital calculations; the disilane is not observed in the vapour, and the observed radical structure is not the lowest energy structure predicted ab initio.
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