| Автор | Kim, Taegyu |
| Автор | Hwang, Jin Soo |
| Автор | Kwon, Sejin |
| Дата выпуска | 2007 |
| dc.description | This paper presents the design, fabrication and evaluation of a micro methanol reformer complete with a heat source. The micro system consists of the steam reforming reactor of methanol, the catalytic decomposition reactor of hydrogen peroxide, and a heat exchanger between the two reactors. In the present study, catalytic decomposition of hydrogen peroxide is used as a process to supply heat to the reforming reactor. The decomposition process of hydrogen peroxide produces water vapor and oxygen as a product that can be used efficiently to operate the reformer/PEMFC system. Cu/ZnO was selected as a catalyst for methanol steam reforming and Pt for the decomposition of hydrogen peroxide. Incipient wetness method was used to load catalysts on a porous support. Catalyst loaded supports were inserted in the cavity made on the glass wafer. The performance of the methanol steam reforming system was measured at various test conditions and the optimum operation condition was sought. At the optimum condition, the hydrogen selectivity was 86.4% and the thermal efficiency was 44.8%. The product gas included 74.1% H2, 24.5% CO2 and 1.4% CO and the total volume production rate was 23.5 ml min<sup>â 1</sup>. This amount of hydrogen can produce 1.5 W of power on a typical PEMFC. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | A MEMS methanol reformer heated by decomposition of hydrogen peroxide |
| Тип | research-article |
| DOI | 10.1039/b700040e |
| Electronic ISSN | 1473-0189 |
| Print ISSN | 1473-0197 |
| Журнал | Lab on a Chip |
| Том | 7 |
| Первая страница | 835 |
| Последняя страница | 841 |
| Аффилиация | Kim Taegyu; Division of Aerospace Engineering, Korea Advanced Institute of Science and Technology |
| Аффилиация | Hwang Jin Soo; Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology |
| Аффилиация | Kwon Sejin; Division of Aerospace Engineering, Korea Advanced Institute of Science and Technology |
| Выпуск | 7 |
| Библиографическая ссылка | Holladay, J. Power Sources, 2004, 130, 111 |
| Библиографическая ссылка | Lu, Lab Chip, 2007, 7, 133 |
| Библиографическая ссылка | Pattekar, J. Microelectromech. Syst., 2004, 13, 7 |
| Библиографическая ссылка | Mitchell, Lab Chip, 2006, 6, 1328 |
| Библиографическая ссылка | Lindstrom, J. Power Sources, 2003, 118, 71 |
| Библиографическая ссылка | Krumpelt, Catal. Today, 2002, 77, 3 |
| Библиографическая ссылка | Delsman, Chem. Eng. Sci., 2004, 59, 4795 |
| Библиографическая ссылка | Park, Catal. Today, 2005, 110, 108 |
| Библиографическая ссылка | Ryi, Chem. Eng. J., 2005, 113, 47 |
| Библиографическая ссылка | Kim, Chem. Eng. J., 2006, 123, 93 |
| Библиографическая ссылка | Agrell, Appl. Catal., A, 2003, 253, 213 |
| Библиографическая ссылка | Kim, J. Micromech. Microeng., 2006, 16, 1752 |
| Библиографическая ссылка | Ishihara, J. Power Sources, 2004, 126, 34 |
