Synthesis and structure of tetrathiophene with a chiral 1,1â ²-binaphthyl kinkElectronic supplementary information (ESI) available: synthesis and characterization data for 1, 2, 4, and 5; crystal packing plots for rac-1. See http://www.rsc.org/suppdata/cc/b0/b007355p/
Rajca, Andrzej; Wang, Hua; Pawitranon, Visa; Brett, Tom J.; Stezowski, John J.; Rajca Andrzej; Department of Chemistry and Center for Materials Research and Analysis, University of Nebraska; Wang Hua; Department of Chemistry and Center for Materials Research and Analysis, University of Nebraska; Pawitranon Visa; Department of Chemistry and Center for Materials Research and Analysis, University of Nebraska; Brett Tom J.; Department of Chemistry and Center for Materials Research and Analysis, University of Nebraska; Stezowski John J.; Department of Chemistry and Center for Materials Research and Analysis, University of Nebraska
Журнал:
Chemical Communications
Дата:
2001
Аннотация:
A chiral oligothiophene, possessing in-chain chirality, was prepared and its racemate was characterized by single crystal X-ray crystallography; the in-chain chiral 1,1â ²-binaphthyl moiety interrupts the Ï -conjugation and affects the solid state properties of the oligothiophene.
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