The compound [Ti4O4{OCH2CH2N(CH3)2}8] containing the new Ti4O4 cluster core
Johnson, Brian F. G.; Klunduk, Marek C.; Oâ Connell, Timothy J.; McIntosh, Calum; Ridland, John; Johnson Brian F. G.; The University Chemical Laboratory, University of Cambridge; Klunduk Marek C.; The University Chemical Laboratory, University of Cambridge; Oâ Connell Timothy J.; The University Chemical Laboratory, University of Cambridge; McIntosh Calum; Synetix, (a member of the ICI group); Ridland John; Synetix, (a member of the ICI group)
Журнал:
Dalton Transactions
Дата:
2001
Аннотация:
Reaction of [Ti(OPr<sup>i</sup>)4] with the bidentate ligand (CH3)2NCH2CH2O<sup>â </sup> (DMEA) followed by controlled hydrolysis yields the new tetranuclear compound [Ti4O4(DMEA)8] involving a novel Ti4O4 central core and three different bonding modes of the DMEA ligand.
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