Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materialsâ The synthetic details for the preparation of 34 are available as supplementary data. For direct electronic access see http://www.rsc.org/suppdata/p1/b0/b007660k/
Ozturk, Turan; Saygili, Nezire; Ozkara, Serife; Pilkington, Melanie; Rice, Craig R.; Tranter, Deborah A.; Turksoy, Figen; Wallis, John D.; Ozturk Turan; Department of Chemistry, TUBITAK â Marmara Research Centre, Department of Chemistry; Saygili Nezire; Department of Chemistry and Physics; Ozkara Serife; Department of Physical Chemistry, Istanbul Technical University; Pilkington Melanie; Department of Chemistry and Physics; Rice Craig R.; Department of Chemistry and Physics; Tranter Deborah A.; Department of Chemistry and Physics; Turksoy Figen; Department of Chemistry, TUBITAK â Marmara Research Centre, Department of Chemistry; Wallis John D.; Department of Chemistry and Physics
Журнал:
Journal of the Chemical Society, Perkin Transactions 1
Дата:
2001
Аннотация:
The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur donor molecules both racemic and enantiopure forms are prepared.
177.4Кб