The coupling of methylene and vinyl ligands at a ruthenium(II) centre
Hill, Anthony F.; Ho, Chean T.; Wilton-Ely, James D. E. T.
Журнал:
Chemical Communications
Дата:
1997
Аннотация:
The reaction of [Ru(CH.dbd6;CH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η<sup>3</sup>-CH2CHCH2)Cl(CO)(PPh3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.
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