A method for olefin inversion via phosphine oxides
Bridges, Alexander J.; Whitham, Gordon H.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1974
Аннотация:
Treatment of epoxides with Ph2PLiâ THF followed by H2O2â AcOH gives, by a single inversion, β-hydroxy-diphenylphosphine oxides; the latter can be fragmented stereospecifically to olefins on treatment with an appropriate base.
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