Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediateElectronic supplementary information (ESI) available: Experimental, crystallographic and computational details. See http://www.rsc.org/suppdata/cc/b4/b405358c/
May, Caleb M.; Archibald, Stephen J.; Bridgeman, Adam J.; Empson, Christopher J.; Hubin, Timothy J.; May Caleb M.; Department of Natural Science, McPherson College; Archibald Stephen J.; Department of Chemistry, University of Hull; Bridgeman Adam J.; Department of Chemistry, University of Hull; Empson Christopher J.; Department of Chemistry, University of Hull; Hubin Timothy J.; Department of Natural Science, McPherson College
Журнал:
Chemical Communications
Дата:
2004
Аннотация:
An unusual copper(ii) complex of a highly rigid and bulky ligand (a macrocycleâ glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.
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