PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complexElectronic supplementary information (ESI) available: Fig. S1: ESI-MS positive spectrum of 2. Fig. S2: 1H NMR spectrum of 2 in the low-field region. Fig. S3: 195Pt{1H} NMR spectrum of 2. Fig. S4: 2-D 1H/195Pt XHCOR NMR spectrum of 2. Fig. S5: IR spectrum of 2 (Nujol mull). Fig. S6: 31P{1H} NMR spectrum of 2. Fig. S7: J-resolved 1H NMR spots of 2. Table S1: Spectroscopic features of 3. See http://www.rsc.org/suppdata/dt/b4/b402180k/
Mastrorilli, Piero; Latronico, Mario; Nobile, Cosimo Francesco; Suranna, Gian Paolo; Fanizzi, Francesco Paolo; Englert, Ulli; Ciccarella, Giuseppe; Mastrorilli Piero; Dipartimento di Ingegneria delle Acque e di Chimica del Politecnico di Bari; Latronico Mario; D. I. F. A., Università della Basilicata; Nobile Cosimo Francesco; Dipartimento di Ingegneria delle Acque e di Chimica del Politecnico di Bari; Suranna Gian Paolo; Dipartimento di Ingegneria delle Acque e di Chimica del Politecnico di Bari; Fanizzi Francesco Paolo; Dip. di Scienze e Tecnologie Biologiche e Ambientali, Università di Lecce; Englert Ulli; Institut für Anorganische Chemie der RWTH; Ciccarella Giuseppe; Dipartimento di Ingegneria dell'Innovazione, University of Lecce
Журнал:
Dalton Transactions
Дата:
2004
Аннотация:
Exposure of solid trans-[Pt(PHCy2)2(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)2H}] (2) as the major product, the formation of which has been followed by NOESY <sup>1</sup>H NMR techniques.
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