| Автор | M.-L. Saboungi |
| Автор | D. L. Price |
| Автор | C. Scamehorn |
| Автор | M. P. Tosi |
| Дата выпуска | 1991-06-01 |
| dc.description | We report a neutron diffraction study of the liquid structure of YCl<sub>3</sub> and combine the structural data with macroscopic melting and transport data to contrast the behaviour of this molten salt with those of SrCl<sub>2</sub>, ZnCl<sub>2</sub> and AlCl<sub>3</sub> as prototypes of different melting mechanisms for ionic materials. A novel melting mechanism for trivalent metal chlorides, leading to a loose disordered network of edge-sharing octahedral units in the liquid phase, is thereby established. The various melting behaviours are related to bonding character with the help of Pettifor's phenomenological chemical scale. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Melting in Trivalent Metal Chlorides |
| Тип | lett |
| DOI | 10.1209/0295-5075/15/3/009 |
| Electronic ISSN | 1286-4854 |
| Print ISSN | 0295-5075 |
| Журнал | EPL (Europhysics Letters) |
| Том | 15 |
| Первая страница | 283 |
| Последняя страница | 288 |
| Выпуск | 3 |
