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Автор G V Golubkov
Автор G K Ivanov
Дата выпуска 1988-06-14
dc.description The quantum approach to the theory of endoergic associative ionisation reactions of atoms within the framework of the multichannel quantum defect method taking account of configurational interaction between the Rydberg and valence dissociative states is developed. It has been shown that the total cross section of the AI reaction near the ionisation threshold is proportional to the energy E measured from the ionisation threshold ( sigma <sub>AI</sub> approximately E). The effect of the resonant quasidiscrete valence states on the ionisation spectrum is studied. As an example, the AI cross section for the reaction N+O to NO<sup>+</sup>+e<sup>-</sup> is calculated. The temperature dependence of the AI thermal rate coefficients over a broad temperature range has been considered. The effect of a strong monochromatic radiation field on the AI reactions has been discussed.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Near-threshold associative ionisation reactions of atoms
Тип paper
DOI 10.1088/0953-4075/21/11/019
Electronic ISSN 1361-6455
Print ISSN 0953-4075
Журнал Journal of Physics B: Atomic, Molecular and Optical Physics
Том 21
Первая страница 2049
Последняя страница 2063
Аффилиация G V Golubkov; Inst. of Chem. Phys., Acad. of Sci., Moscow, USSR
Аффилиация G K Ivanov; Inst. of Chem. Phys., Acad. of Sci., Moscow, USSR
Выпуск 11

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