Corrected oscillator strengths for the transition elements
T M Luke; T M Luke; Dept. of Phys. & Astron., Univ. Coll. London, UK
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1988-06-28
Аннотация:
Oscillator strength calculations for the transition elements are complicated by the occurrence of many strongly coupled terms from a single configuration. For example, there are nine <sup>2</sup>F<sup>o</sup> terms in the 3d<sup>4</sup>4p configuration of the vanadium sequence. Using the specific example of the transition 3d<sup>4</sup>4s <sup>4</sup>H to 3d<sup>4</sup>4p <sup>4</sup>G<sup>o</sup> in Cr II, it is shown that calculations having poor energy separations for the four 3d<sup>4</sup>4p terms are very unreliable but, if corrected for energy spacing, a calculation using reasonable but rather simple wavefunctions is as good as one using considerably more elaborate forms.
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