Model-potential calculation of lifetimes of Rydberg states of alkali atoms
Xinghong He; Baiwen Li; Aiqiu Chen; Chengxiu Zhang; Xinghong He; Lab. of Magnetic Resonance & Atomic & Molecular Phys., Wuhan Inst. of Phys., Acad. Sinica, China; Baiwen Li; Lab. of Magnetic Resonance & Atomic & Molecular Phys., Wuhan Inst. of Phys., Acad. Sinica, China; Aiqiu Chen; Lab. of Magnetic Resonance & Atomic & Molecular Phys., Wuhan Inst. of Phys., Acad. Sinica, China; Chengxiu Zhang; Lab. of Magnetic Resonance & Atomic & Molecular Phys., Wuhan Inst. of Phys., Acad. Sinica, China
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1990-02-28
Аннотация:
A comprehensive set of transition probabilities and radiative lifetimes of Rydberg states of alkali atoms (for Na, K, Cs, n<or=30; and for Rb, n<or=50) is obtained by using a simple, exactly solvable potential model for atoms. The results agree well with the available experimental values and other theoretical ones. Scaling relations for evaluating transition probabilities and lifetimes of high Rydberg states are also discussed. The well known (n*)<sup>-5</sup> scaling law of the transition probabilities A<sub>n(inf) not=n(inf)</sub>/ with n' approximately=n>>1 is generally valid; however, the authors also find deviations from this law for some d to p and f to d transitions for Rb. A third-power polynomial is found to be better than the currently used exponential scaling law in predicting the lifetimes of even higher excited states.
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