Collisional redistribution of polarized radiation for Sr-Ar(He) systems: a numerical comparison of the semiclassical decoupling/locking model to exact results
R J Bieniek; P S Julienne; F Rebentrost; R J Bieniek; Dept. of Phys., Missouri Univ., Rolla, MO, USA; P S Julienne; Dept. of Phys., Missouri Univ., Rolla, MO, USA; F Rebentrost; Dept. of Phys., Missouri Univ., Rolla, MO, USA
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1991-12-28
Аннотация:
Semiclassical formulations of collisional redistribution of polarized radiation are presented at several levels of approximation, from full classical path coupled equations to the locking/decoupling model. These are numerically tested against the results of a quantum mechanical coupled-channels formalism, by the comparison of polarization curves in both spectral wings of the Sr(<sup>1</sup>S<sub>0</sub>-<sup>1</sup>P<sub>1</sub>) transition, with Ar and He as collisional perturbers. It is found that the locking/decoupling model can often produce good agreement with exact results if the effects due to trajectories and multiple Condon points are treated properly. Significant discrepancies due to the Condon approximation used by the model are seen in the near blue wing of the spectra and attributed to antistatic effects.
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