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Автор X Urbain
Автор J J Blange
Автор H A Dijkerman
Автор H Rudolph
Автор H G M Heideman
Дата выпуска 1994-06-14
dc.description Using a new approach the authors have determined the internal (vibrational) energy distribution of the molecular ions formed in the collisional associative ionization (AI) between thermal Na*(3p) atoms. The method is based on the wavelength dependent measurement of the Na<sup>+</sup> ions formed in the photodissociation of the Na<sub>2</sub><sup>+</sup> ions. The authors find that there is a substantial vibrational excitation and even a population inversion, with the upsilon =2 to 4 levels predominantly populated. These findings are in good agreement with previous experimental results obtained through electron detection, and with the detailed ab initio calculations by Dulieu et al (1991). The present method should prove itself suitable under conditions where other methods are difficult to apply, e.g. in collisions between cold atoms.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Internal energy distribution in Na<sub>2</sub><sup>+</sup> ions formed through associative ionization as probed by photofragmentation
Тип lett
DOI 10.1088/0953-4075/27/11/003
Electronic ISSN 1361-6455
Print ISSN 0953-4075
Журнал Journal of Physics B: Atomic, Molecular and Optical Physics
Том 27
Первая страница L245
Последняя страница L250
Аффилиация X Urbain; Debye Inst., Utrecht Univ., Netherlands
Аффилиация J J Blange; Debye Inst., Utrecht Univ., Netherlands
Аффилиация H A Dijkerman; Debye Inst., Utrecht Univ., Netherlands
Аффилиация H Rudolph; Debye Inst., Utrecht Univ., Netherlands
Аффилиация H G M Heideman; Debye Inst., Utrecht Univ., Netherlands
Выпуск 11

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