Molecular rotation and kinetic collisions: a systematic study of CH<sub>3</sub>F in the nu <sub>4</sub> band
H I Bloemink; J M Boon-Engering; P L Chapovsky; L J F Hermans; E R Eliel; H I Bloemink; Huygens Lab., Leiden Univ., Netherlands; J M Boon-Engering; Huygens Lab., Leiden Univ., Netherlands; P L Chapovsky; Huygens Lab., Leiden Univ., Netherlands; L J F Hermans; Huygens Lab., Leiden Univ., Netherlands; E R Eliel; Huygens Lab., Leiden Univ., Netherlands
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1994-10-14
Аннотация:
In order to determine the effect of molecular rotation on gas kinetic collisions, light-induced drift measurements were performed on CH<sub>3</sub>F in the nu <sub>4</sub> rovibrational band. Data were taken for a large set of transitions of the type v=0 to 1, Delta J=1, Delta K=1 over a range of values of J or K. Systematic trends in the J- and K-dependence of the kinetic collision rate have been observed. For Kr and CH<sub>3</sub>Cl as collision partners the K-dependence is found to be large and nearly linear in K, whereas the J-dependence is found to be small. We present a theoretical model to describe the dependence on the rotational quantum numbers of the relative change in collision rate upon excitation; this model is in satisfying agreement with the experimental results.
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