On the secondly quantized theory of the many-electron atom
Gediminas Gaigalas; Zenonas Rudzikas; Gediminas Gaigalas; State Institute of Theoretical Physics and Astronomy, A Gostauto 12, 2600 Vilnius, Lithuania; Zenonas Rudzikas; State Institute of Theoretical Physics and Astronomy, A Gostauto 12, 2600 Vilnius, Lithuania
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1996-08-14
Аннотация:
The traditional theory of many-electron atoms and ions is based on the coefficients of fractional parentage and matrix elements of tensorial operators, composed of unit tensors. The calculation of spin-angular coefficients of radial integrals appearing in the expressions of matrix elements of arbitrary physical operators of atomic quantities has two main disadvantages: (i) the numerical codes for the calculation of spin-angular coefficients are usually very time consuming; (ii) f-shells are often omitted from programs for matrix element calculations since the tables for their coefficients of fractional parentage are very extensive. The authors assume that a series of difficulties persisting in the traditional approach to the calculation of spin-angular parts of matrix elements can be avoided by using this secondly quantized methodology, based on angular momentum theory, on the concept of the irreducible tensorial sets, on a generalized graphical method, on quasispin and on the reduced coefficients of fractional parentage.
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