Analytical approach to the helium-atom ground state using correlated wavefunctions
S Bhattacharyya; A Bhattacharyya; B Talukdar; N C Deb
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1996-03-14
Аннотация:
A realistic three-parameter correlated wavefunction is used to construct an exact analytical expression for the expectation value of the helium-atom Hamiltonian expressed in the interparticle coordinates. The parameters determined variationally are found to satisfy the orbital and correlation cusp conditions to a fair degree of accuracy and yield a value for the ground-state energy which is in good agreement with the exact result.
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