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Автор P S Krstic
Автор C O Reinhold
Автор D R Schultz
Дата выпуска 1998-02-28
dc.description We have determined the minimum set of molecular states and couplings that can explain the origin of ubiquitous oscillations in the excitation cross section for low-energy ion - atom collisions which have recently drawn significant theoretical and experimental attention. To this end, the model of non-adiabatic radial couplings between quasimolecular states in slow heavy particle collisions is reformulated using the hidden-crossings theory to circumvent certain inherent shortcomings of the conventional molecular orbital close-coupling approach. We find that four diabatic states, two of which are formed by appropriate S superseries of branch points of the complex adiabatic quasimolecular energy surface, are required to represent the physical mechanism responsible for the oscillations. In particular, the oscillations originate from the interference of two paths along these terms through which the initial state is promoted to the same final quasimolecular state.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Interference oscillations in the excitation cross section for slow ion - hydrogen collisions
Тип lett
DOI 10.1088/0953-4075/31/4/007
Electronic ISSN 1361-6455
Print ISSN 0953-4075
Журнал Journal of Physics B: Atomic, Molecular and Optical Physics
Том 31
Первая страница L155
Последняя страница L163
Аффилиация P S Krstic; Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6373, USA
Аффилиация C O Reinhold; Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6373, USA
Аффилиация D R Schultz; Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6373, USA
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