| Автор | D L Hansen |
| Автор | J Cotter |
| Автор | G R Fisher |
| Автор | K T Leung |
| Автор | R Martin |
| Автор | P Neill |
| Автор | R C C Perera |
| Автор | M Simon |
| Автор | Y Uehara |
| Автор | B Vanderford |
| Автор | S B Whitfield |
| Автор | D W Lindle |
| Дата выпуска | 1999-06-14 |
| dc.description | Relaxation dynamics of CH<sub>3</sub>Cl following core-shell photoexcitation in the neighbourhood of the chlorine K-edge ( 2.8 keV) were studied via multi-ion coincidence measurements using a time-of-flight mass spectrometer. The data provide evidence for sequential fragmentation moderated by Coulombic interactions among the fragments. The sequential nature of the fragmentation indicates that chemical forces, especially between the carbon and chlorine atoms, are dominant in determining the kinematics of the fragmentation. This is especially true on resonance where fast dissociation is observed following electron excitations to the 8a<sub>1</sub> antibonding orbital. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Multi-ion coincidence measurements of methyl chloride following photofragmentation near the chlorine K-edge |
| Тип | paper |
| DOI | 10.1088/0953-4075/32/11/312 |
| Electronic ISSN | 1361-6455 |
| Print ISSN | 0953-4075 |
| Журнал | Journal of Physics B: Atomic, Molecular and Optical Physics |
| Том | 32 |
| Первая страница | 2629 |
| Последняя страница | 2647 |
| Выпуск | 11 |
