| Автор | Vladimir I Pupyshev |
| Автор | Andrei V Scherbinin |
| Дата выпуска | 1999-10-14 |
| dc.description | A general asymptotic estimate is derived for the molecular energy level shifts caused by the encapsulation of the system into a spherical impenetrable box of a large radius R. The value of the shift is proved to be exponentially small with respect to both R and B<sub>i</sub> = 2(2I<sub>i</sub>)<sup>1/2</sup>, where I<sub>i</sub> is the lowest ionization potential in the ith state of the non-confined `free' system. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Molecular energy level shifts in large boxes: use of the Kirkwood-Buckingham method |
| Тип | paper |
| DOI | 10.1088/0953-4075/32/19/304 |
| Electronic ISSN | 1361-6455 |
| Print ISSN | 0953-4075 |
| Журнал | Journal of Physics B: Atomic, Molecular and Optical Physics |
| Том | 32 |
| Первая страница | 4627 |
| Последняя страница | 4634 |
| Аффилиация | Vladimir I Pupyshev; Laboratory of Molecular Structure and Quantum Mechanics, Department of Chemistry, Moscow State University, Moscow, 119899, Russian Federation |
| Аффилиация | Andrei V Scherbinin; Laboratory of Molecular Structure and Quantum Mechanics, Department of Chemistry, Moscow State University, Moscow, 119899, Russian Federation |
| Выпуск | 19 |
