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Автор David B Thompson
Автор De Ji
Автор Shih-Ying Chen
Автор David M Hanson
Дата выпуска 1999-12-28
dc.description Monochromatic synchrotron radiation was used to selectively excite core electrons of the carbon and oxygen atoms in acetaldehyde, propionaldehyde and acetone, creating neutral core-excited resonance states. Electron energy spectra associated with autoionization of the strong resonances in these molecules were collected. The character of each resonance state was deduced from its decay spectrum. Among other conclusions, this analysis suggests that the highest-energy, intense carbon core-excited resonance in acetaldehyde arises from excitation of two degenerate core-excited states, one with the core-hole site located on the carbonyl carbon and the other with the core-hole site located on the alkyl carbon.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Excitation and decay spectra of core-excited resonances in acetaldehyde, propionaldehyde and acetone
Тип paper
DOI 10.1088/0953-4075/32/24/308
Electronic ISSN 1361-6455
Print ISSN 0953-4075
Журнал Journal of Physics B: Atomic, Molecular and Optical Physics
Том 32
Первая страница 5711
Последняя страница 5724
Аффилиация David B Thompson; Department of Chemistry, State University of New York, Stony Brook, NY 11794-3400, USA
Аффилиация De Ji; Department of Chemistry, State University of New York, Stony Brook, NY 11794-3400, USA
Аффилиация Shih-Ying Chen; Department of Chemistry, State University of New York, Stony Brook, NY 11794-3400, USA
Аффилиация David M Hanson; Department of Chemistry, State University of New York, Stony Brook, NY 11794-3400, USA
Выпуск 24

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