Ab initio study of charge transfer in low-energy collisions with helium
P C Stancil; N J Clarke; B Zygelman; D L Cooper
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
1999-03-28
Аннотация:
Charge transfer cross sections for collisions of ground state and excited state ) with atomic helium are presented for energies less than 250 eV . Using a fully quantum mechanical, molecular-orbital, close-coupling approach, the cross sections are calculated in a diabatic representation. Completely ab initio adiabatic potentials and nonadiabatic radial coupling matrix elements obtained with the spin-coupled valence-bond method are utilized. Rate coefficients for temperatures between 100 and 100 000 K and cross sections for collisions with isotopic are presented. Results for the reverse process, , are also given.
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