Автор |
N G Adams |
Автор |
D Smith |
Автор |
D Grief |
Дата выпуска |
1979-03-14 |
dc.description |
Measurements are reported of the reactions of the ground (<sup>3</sup>P) and metastable electronically excited (<sup>1</sup>D<sub>2</sub> and <sup>1</sup>S<sub>0</sub>) states of Xe<sup>2+</sup> ions with several atoms (Ar and Xe) and molecules (H<sub>2</sub>, N<sub>2</sub>, O<sub>2</sub> and CO<sub>2</sub>) at 300K. The data were obtained using a selected-ion-flow-tube (SIFT) apparatus. State selection was achieved by introducing suitable 'chemical-filter' gases into the flow tube. The rate coefficients for the reactions with the molecules were large with the exception of some of the reactions of the <sup>1</sup>S<sub>0</sub> state. Conversely, the atom reactions were generally slow except for the <sup>3</sup>P state reaction with Ar in which a favourable pseudo-energy resonance must occur. All the molecular reactions proceeded via single-charge transfer and in the <sup>1</sup>D<sub>2</sub> reactions with molecules, dissociation of the product ion was usually observed. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Single-charge transfer reactions of the ground and metastable states of Xe<sup>2+</sup> at 300K |
Тип |
paper |
DOI |
10.1088/0022-3700/12/5/023 |
Print ISSN |
0022-3700 |
Журнал |
Journal of Physics B: Atomic and Molecular Physics |
Том |
12 |
Первая страница |
791 |
Последняя страница |
800 |
Аффилиация |
N G Adams; Dept. of Space Res., Univ. of Birmingham, Birmingham, UK |
Аффилиация |
D Smith; Dept. of Space Res., Univ. of Birmingham, Birmingham, UK |
Аффилиация |
D Grief; Dept. of Space Res., Univ. of Birmingham, Birmingham, UK |
Выпуск |
5 |