A simple model of configuration interaction of ionic and covalent states
V I Osherov; L V Poluyanov; V I Osherov; Inst. of Chem. Phys., Acad. of Sci., Moscow, USSR; L V Poluyanov; Inst. of Chem. Phys., Acad. of Sci., Moscow, USSR
Журнал:
Journal of Physics B: Atomic and Molecular Physics
Дата:
1980-12-14
Аннотация:
A simple analytical model of configuration interaction of ionic and covalent states is developed. The model describes the bound states of an electron in a Coulomb field and N point potentials (N=1 and 2). In this model the adiabatic ionic-covalent splitting is found as a function of the principal quantum number and the ionisation potential of the donor atom and the electron affinity of the acceptor atom.
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