Calculation of vibrational excitation of N<sub>2</sub> by electron impact at 5-50 eV using extended-basis-set Hartree-Fock wavefunctions
J R Rumble Jr; D G Truhlar; M A Morrison; J R Rumble Jr; Joint Inst. for Lab. Astrophys., Univ. of Colorado, Boulder, CO, USA; D G Truhlar; Joint Inst. for Lab. Astrophys., Univ. of Colorado, Boulder, CO, USA; M A Morrison; Joint Inst. for Lab. Astrophys., Univ. of Colorado, Boulder, CO, USA
Журнал:
Journal of Physics B: Atomic and Molecular Physics
Дата:
1981-04-28
Аннотация:
The cross sections 0 to 0, 0 to 1 and 1 to 2 for vibrational excitation of N<sub>2</sub> by electron impact at 5, 10, 20, 30 and 50 eV are calculated in a static-exchange-polarisation model. The calculations are based on the Hartree-Fock target wavefunctions of Cade, Sales and Wahl (1966) for the static potential and for the Hara (1967) free-electron-gas exchange potential. Target charge polarisation is included by the effective polarisation potential of Morrison and Collins (1978), scaled as a function of internuclear distance by the polarisabilities. The calculated cross sections are well converged with respect to channels. The results show clearly both the low-energy Pi <sub>g</sub> resonance and the intermediate-energy Sigma <sub>u</sub> resonance.
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