| Автор | K G Dyall |
| Дата выпуска | 1983-09-14 |
| dc.description | A method is presented for the calculation of populations following an ionisation event of individual states of more than one degree of ionisation, in the sudden approximation, using only bound-state wavefunctions. It is applied to 1s ionisation on argon, where it is shown that single excitation is twice as probable as single ionisation from the outer shell, and doubly-excited or singly-excited singly-ionised states have nonnegligible populations. Relativistic effects are found to substantially mix states of different LS symmetry, so the monopole selection rules for shake-up/shake-off in LS coupling are not strictly obeyed. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Shake theory predictions of excited-state populations following 1s ionisation in argon |
| Тип | paper |
| DOI | 10.1088/0022-3700/16/17/008 |
| Print ISSN | 0022-3700 |
| Журнал | Journal of Physics B: Atomic and Molecular Physics |
| Том | 16 |
| Первая страница | 3137 |
| Последняя страница | 3147 |
| Аффилиация | K G Dyall; Theoretical Chem. Dept., Oxford Univ., Oxford, UK |
| Выпуск | 17 |
