A comment on the calculation of atomic energy levels in LS coupling using relativistic radial integrals
K G Dyall; K G Dyall; Dept. of Chem., Monash Univ., Clayton North, Vic., Australia
Журнал:
Journal of Physics B: Atomic and Molecular Physics
Дата:
1985-04-14
Аннотация:
Relativistic effects have been included in non-relativistic term energies in some recent work by relating to non-relativistic radial integrals. It is seen that the need for a non-relativistic term energy is principally one of labelling the eigenstates of the atomic system according to some single-configuration coupling scheme, which could be achieved by a coupling transformation from the basic jj-coupled schemes used in relativistic atomic structure calculations.
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