| Автор | M A Baig |
| Автор | J P Connerade |
| Автор | J Hormes |
| Дата выпуска | 1986-05-28 |
| dc.description | Reports new high-resolution measurements of the photoabsorption spectrum of C<sub>2</sub>H<sub>5</sub>I, in which prominent autoionising resonances have been observed. The spectrum is similar in some respects to the reported spectrum of CH<sub>3</sub>I (Baig et al., 1981). Rydberg series are found to the <sup>2</sup>E limits, arising from excitation of a lone-pair pi orbital. The authors have performed a graphical Lu-Fano analysis of the series converging to <sup>2</sup>E<sub>3/2</sub> by comparison with Xe I and CH<sub>3</sub>I. The authors are able to extract from their data a quasi-atomic ordering of Rydberg excitations. Above the <sup>2</sup>E<sub>3/2</sub> threshold, the authors have applied the Dubau-Seaton formula to interpret the spectrum, and they can tentatively ascribe most of the observed width to autoionisation. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Autoionisation resonances in the photoabsorption spectrum of C<sub>2</sub>H<sub>5</sub>I |
| Тип | lett |
| DOI | 10.1088/0022-3700/19/10/003 |
| Print ISSN | 0022-3700 |
| Журнал | Journal of Physics B: Atomic and Molecular Physics |
| Том | 19 |
| Первая страница | L343 |
| Последняя страница | L347 |
| Аффилиация | M A Baig; Phys. Inst., Bonn Univ., West Germany |
| Аффилиация | J P Connerade; Phys. Inst., Bonn Univ., West Germany |
| Аффилиация | J Hormes; Phys. Inst., Bonn Univ., West Germany |
| Выпуск | 10 |
