A revised Rydberg formula for two-electron systems: I. (core)ns<sup>2</sup>
Hung-tai Wang; Hung-tai Wang; Dept. of Chem., Chicago Univ., IL, USA
Журнал:
Journal of Physics B: Atomic and Molecular Physics
Дата:
1986-11-14
Аннотация:
An empirically fitted Rydberg-like formula for two-electron systems is described. The resultant revised Rydberg formula (RRF) contains two parameters: the screening constant sigma and the correction to the effective quantum number mu . They can concisely correlate a large number of (core)n/sub /il<sup>2</sup> binding energies. Both are simple functions of the core charge Z, the core configuration and l. The accuracy of the RRF in calculating the two-electron binding energies of over 50 (core)n/sub /is<sup>2</sup> species is demonstrated and the physical interpretations of sigma <sub>s</sub> and mu <sub>s</sub> are discussed.
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