| Автор | I Novak |
| Автор | J M Benson |
| Автор | A W Potts |
| Дата выпуска | 1987-07-28 |
| dc.description | Photoelectron spectra of molecular WF<sub>6</sub> have been recorded with photons in the energy range 22-90 eV using synchrotron radiation. In addition to the previously observed valence orbitals, the F 2s and W 4f and 5p core levels have been observed and their ionisation energies compared with available MS X alpha and relativistic Dirac-Slater quantum mechanical calculations. Branching ratios have been calculated for all orbitals in order to gain an insight into their localisation properties. Selective enhancement of the branching ratios of the 2a<sub>1g</sub>+1t<sub>2g</sub> and 2t<sub>1u</sub> orbitals has been observed and attributed to autoionisation including a 5p-5d resonance in tungsten. Strong shape resonance effects produce enhancements in branching ratios for the 3t<sub>1u</sub>+1t<sub>2u</sub> and 2e<sub>g</sub> orbitals. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | A UV photoelectron study of WF<sub>6</sub> using synchrotron radiation |
| Тип | paper |
| DOI | 10.1088/0022-3700/20/14/012 |
| Print ISSN | 0022-3700 |
| Журнал | Journal of Physics B: Atomic and Molecular Physics |
| Том | 20 |
| Первая страница | 3395 |
| Последняя страница | 3403 |
| Аффилиация | I Novak; Dept. of Phys., King's Coll. London, UK |
| Аффилиация | J M Benson; Dept. of Phys., King's Coll. London, UK |
| Аффилиация | A W Potts; Dept. of Phys., King's Coll. London, UK |
| Выпуск | 14 |
