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Автор D T Birtwistle
Автор A Herzenberg
Дата выпуска 1971-01-01
dc.description The vibrational excitation of N<sub>2</sub> molecules by resonance scattering of electrons of 2-3 eV is calculated with a compound state model, that is on the assumption that the mechanism is e+N<sub>2</sub> to N<sub>2</sub><sup>-</sup> to N<sub>2</sub>+e'. The complex electronic energy of the N<sub>2</sub><sup>-</sup> ion is treated parametrically, the essential new point being that Gamma /h(cross), the autoionization rate, varies with the separation of the nuclei. The variation comes from the dependence of the angular momentum barrier on the energy of the emitted electron. Good agreement is obtained with the experimental energy dependence of cross sections with reasonable values of the parameters. Calculations have also been done to illustrate the transition to the impulse limit as Gamma is increased, and to the compound molecule limit as Gamma is reduced.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Vibrational excitation of N<sub>2</sub> by resonance scattering of electrons
Тип paper
DOI 10.1088/0022-3700/4/1/009
Print ISSN 0022-3700
Журнал Journal of Physics B: Atomic and Molecular Physics
Том 4
Первая страница 53
Последняя страница 70
Аффилиация D T Birtwistle; Univ. Manchester, UK
Аффилиация A Herzenberg; Univ. Manchester, UK
Выпуск 1

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