Semi-empirical Auger electron energies. III. Solids
F P Larkins; F P Larkins; Dept. of Chem., Monash Univ., Clayton, Vic., Australia
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1977-07-14
Аннотация:
For pt.II see J. Phys. B., vol.9, p.881 (1976). A general semi-empirical method presented earlier by the present author to calculate Auger-electron energies within an intermediate-coupling framework has been refined to incorporate a solid-state correction term. This term is derived from an atomic Hartree-Fock screening model outlined in the preceding paper. Experimental and theoretical results for a range of vapour phase and solid phase elemental systems embracing a wide diversity of Auger transition series are presented to illustrate the usefulness of the approach. For most systems, agreement is within 1-2 eV, with the maximum discrepancies being near 5 eV. A table of solid-state correction values for elements 10-102 is presented to modify the K-LL energies reported previously.
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