Point-charge approximation of tetragonal Yb<sup>3+</sup> and Ce<sup>3+</sup> centres in CaF<sub>2</sub>
Sung Ho Choh; Sung Ho Choh; Internat. Centre for Theoretical Phys., Trieste, Italy
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1977-05-14
Аннотация:
The perturbation to the cubic crystalline field at rare-earth ions substituting the cation in CaF<sub>2</sub> is treated as a point-charge Coulomb field of the compensating ion. The cubic field energy states and the local charge compensation have enabled the author to calculate the wavefunction and g-values of Yb<sup>3+</sup> and Ce<sup>3+</sup> with tetragonal symmetry in CaF<sub>2</sub>. The results for Yb<sup>3+</sup> turn out to be in reasonable agreement with experimental g-values, while those for Ce<sup>3+</sup> seem not unsatisfactory.
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