Raman scattering at structural phase transitions
Y Yacoby; R A Cowley; T J Hosea; D J Lockwood; W Taylor; Y Yacoby; Dept. of Phys., Univ. of Edinburgh, Edinburgh, UK; R A Cowley; Dept. of Phys., Univ. of Edinburgh, Edinburgh, UK; T J Hosea; Dept. of Phys., Univ. of Edinburgh, Edinburgh, UK; D J Lockwood; Dept. of Phys., Univ. of Edinburgh, Edinburgh, UK; W Taylor; Dept. of Phys., Univ. of Edinburgh, Edinburgh, UK
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1978-12-24
Аннотация:
The Raman scattering of light from the ferroelectric fluctuations of the uniaxial ferroelectric lead germanate is analysed and found to be well described by models for which the self-energy has appreciable dispersion at frequencies comparable with the soft-mode linewidth. A model is developed to calculate the self-energy arising from phonon-density fluctuations of the modes belonging to the same branch. The model shows that this contribution to the self-energy of the soft mode is particularly large if the modes with which it is interacting are overdamped. In detail, however, the model suggests that close to T<sub>c</sub> there is an appreciable contribution to the Raman scattering from the interference terms between the one- and two-phonon scattering.
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