| Автор | T Iida |
| Автор | Y Nakaoka |
| Автор | J P von der Weid |
| Автор | M A Aegerter |
| Дата выпуска | 1980-02-29 |
| dc.description | The electronic structure of the self-trapped exciton (STE) in caesium iodide is investigated by a semi-empirical molecular-orbital method. The STE states are constructed by considering the relaxed electronic states of a cluster composed of an anionic diatomic I<sub>2</sub><sup>-</sup> molecule surrounded by its nearest-neighbour Cs<sup>+</sup> ions. For the electronic states, the 6s and 5d orbitals of the Cs<sup>+</sup> ions are taken into account. Two types of STE states are obtained; the lower level manifold of each one is composed of a split triplet state and a singlet state. Both give rise to pi -emissions with a rather long radiative lifetime. The general expressions for the magnetic circular polarisation, the magnetic linear polarisation and the lifetime of the emissions are derived and discussed. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Self-trapped exciton in caesium iodide. I. Theory |
| Тип | paper |
| DOI | 10.1088/0022-3719/13/6/009 |
| Print ISSN | 0022-3719 |
| Журнал | Journal of Physics C: Solid State Physics |
| Том | 13 |
| Первая страница | 983 |
| Последняя страница | 992 |
| Аффилиация | T Iida; Dept. of Phys., Osaka City Univ., Osaka, Japan |
| Аффилиация | Y Nakaoka; Dept. of Phys., Osaka City Univ., Osaka, Japan |
| Аффилиация | J P von der Weid; Dept. of Phys., Osaka City Univ., Osaka, Japan |
| Аффилиация | M A Aegerter; Dept. of Phys., Osaka City Univ., Osaka, Japan |
| Выпуск | 6 |
