Surface layer in ferroelectric KTa<sub>1-x</sub>Nb<sub>x</sub>O<sub>3</sub>
J P Ansermet; D Rytz; A Chatelain; U T Hochli; H E Weibel; J P Ansermet; Lab. de Phys. Experimentale, Ecole Polytech. Federale de Lausanne, Lausanne, Switzerland; D Rytz; Lab. de Phys. Experimentale, Ecole Polytech. Federale de Lausanne, Lausanne, Switzerland; A Chatelain; Lab. de Phys. Experimentale, Ecole Polytech. Federale de Lausanne, Lausanne, Switzerland; U T Hochli; Lab. de Phys. Experimentale, Ecole Polytech. Federale de Lausanne, Lausanne, Switzerland; H E Weibel; Lab. de Phys. Experimentale, Ecole Polytech. Federale de Lausanne, Lausanne, Switzerland
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1981-10-30
Аннотация:
Acoustic-resonance and dielectric susceptibility measurements are reported for thin plates of KT<sub>1-x</sub>Nb<sub>x</sub>O<sub>3</sub> (0.02<or=x<or=0.03) crystals. A thickness dependence is observed and discussed in terms of a surface-layer model, where the surface of the plates exhibits both dielectric and elastic properties different from those of the bulk-like centre. Surface layer thicknesses of (15+or-5) mu m are found, independent of temperature from T<sub>c</sub>+5 to T<sub>c</sub>+270K in a sample with T<sub>c</sub>=30K and x=0.02. They are also independent of surface treatment, be it etching, lapping or no treatment at all (in the case of a natural surface). Pinning of dislocations at the surface is proposed as the probable origin of the surface layer, and, from the absence of critical effects, the existence of a polar surface of macroscopic dimension above T<sub>c</sub> is excluded.
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