Cubic to tetragonal structural phase transition in K<sub>2</sub>OsCl<sub>6</sub> as studied by chlorine nuclear quadrupole resonance: precursor effects in the cubic phase
R L Armstrong; M E Ramia; R L Armstrong; Dept. of Phys., Toronto Univ., Ont., Canada; M E Ramia; Dept. of Phys., Toronto Univ., Ont., Canada
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1985-05-30
Аннотация:
Chlorine nuclear quadrupole resonance absorption lineshapes are reported for powder and single-crystal samples of the antifluorite K<sub>2</sub>OsCl<sub>6</sub> for a range of temperatures above the cubic to tetragonal phase transition. The temperature dependence of the lineshape and its integrated intensity, as well as the isotope independence of the results, provide clear evidence of precursor effects associated with nonlinear anharmonic behaviour. The results suggest that the detailed dynamics associated with the precursor clusters is sensitive to whether point defects or dislocations are dominant as the primary cause of line broadening.
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